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Solution. Verified by Toppr. When phenol reacts with chloroform in the presence of bases (N a O H / K O H), an aldehyde (− C H O) group gets introduced in the ring at a position ortho to the phenolic group and salicylaldehyde is formed. This reaction is called the Reimer-Tiemann reaction. Was this answer helpful?
Explain the following reactions with suitable example:(a) Reimer-Tiemann reaction(b) Cannizaro reaction(c) Aldol condensation(d) Sandmeyer reaction. View Solution. Q 5.
This reaction is called the Reimer-Tiemann reaction. b) In the above image, structure (1) is A and structure (2) is B. We can see that the structure(1) has Oh group directly attached to the aromatic ring creating an " enol" system which shows violet colour with ferric chloride solution while the benzyl alcohol will not show any reaction with the solution.
This reaction is known as the Reimer-Tiemann reaction. The intermediate is hydrolyzed in presence of alkalis to produce salicylaldehyde. (ii) Kolbe's reaction → When phenol is treated with sodium hydroxide, sodium phenoxide is produced. This sodium phenoxide when treated with carbon dioxide, followed by acidification, undergoes electrophilic ...
In Reimer-Tiemann reaction the major product obtained is: View Solution. Click here:point_up_2:to get an answer to your question :writing_hand:in reimer tiemann reaction dichlorocarbene acts as.
Write the following reaction: Reimer-Tiemann reaction. When phenol reacts with chloroform in the presence of bases (NaOH/KOH), an aldehyde (−CHO) group gets introduced in the ring at a position ortho to the phenolic group and salicylaldehyde is formed. This reaction is called the Reimer-Tiemann reaction. Was this answer helpful?
Explain Kolbe-Schmitt reaction and Fries-rearrangement reaction. Explain the following with an example. (i) Kolbes reaction. (ii) Reimer-Tiemann reaction. (iii) Williamson ether synthesis. (iv) Unsymmetrical ether. Assertion :Phenol undergo Kolbe reaction, ethanol does not. Reason: Phenoxide ion is more basic than ethoxide ion.
Explain the following reactions: (i) Reimer - Tiemann reaction. (ii) Williamson's ether synthesis. by treatment with NaOH/chloroform. Thus Reimer-Tiemann reaction. involves ortho-formylation of phenols. Major product is ortho isomer which is separated from para isomer by steam distillation. Ortho isomer predominates due to its stability due to ...
Explain the following with an example. (i) Kolbe’s reaction. (ii) Reimer-Tiemann reaction. (iii) Williamson ether synthesis.
View Solution. Q 3. Explain the following with an example. (i) Kolbes reaction. (ii) Reimer-Tiemann reaction. (iii) Williamson ether synthesis. (iv) Unsymmetrical ether. View Solution. Q 4.
